The Use of Polymer Supports in Organic Synthesis. II. The Syntheses of Monoethers of Symmetrical Diols
Author(s) -
Jack Y. Wong,
Clifford C. Leznoff
Publication year - 1973
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v73-367
Subject(s) - chemistry , ether , polymer , group (periodic table) , blocking (statistics) , polymer chemistry , organic chemistry , mathematics , statistics
An insoluble polymer support system was used as a unique method of blocking one functional group of a completely symmetrical difunctional compound. The monotetrahydropyranyl and monotrityl ethers of the symmetrical diols, HO—(CH2) n —OH, where n = 2,4,6,8, and 10, were prepared. Reaction conditions for the preparation of the monotetrahydropyranyl ether of 1,10-decanediol were optimized.
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