Open AccessA Determination of σ+ Values for the Pyridine Aza Group
Author(s) -
Trevor J. Broxton,
Graeme Butt,
Leslie W. Deady,
Swee Hin Toh,
R. D. Topsom,
Alfred Fischer,
Michael W. Morgan
Publication year - 1973
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v73-243
Subject(s) - chemistry , solvolysis , pyridine , acetone , methanol , group (periodic table) , medicinal chemistry , organic chemistry , hydrolysis
From the solvolysis of the pyridyldimethylcarbinyl chlorides in acetone–water and in methanol, σ + values of 0.73, 0.57, 1.13 and 0.72, 0.45, 1.14, respectively, are derived for the 2-, 3-, and 4-aza groups.
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