Open AccessThe Radiochemistry of Organoiron Compounds. III. Fe(CO)5–Cyclopentadiene Solutions
Author(s) -
W. Kanellakopulos-Drossopulos,
D. R. Wiles
Publication year - 1973
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v73-033
Subject(s) - cyclopentadiene , chemistry , dissociation (chemistry) , yield (engineering) , monomer , atom (system on chip) , tetracoordinate , medicinal chemistry , inorganic chemistry , photochemistry , organic chemistry , polymer , catalysis , materials science , computer graphics (images) , computer science , metallurgy , planar , embedded system
Nucleogenesis of 59 Fe gives iron atoms which react with monomeric cyclopentadiene to produce 59 FeCp 2 , either in liquid or solid solutions, but do not react appreciably with dimeric cyclopentadiene. This is taken as showing that local thermal effects of the nuclear reactions are ineffective in causing the dissociation (C 5 H 6 ) 2 → 2C 5 H 6 . The concentration dependence of the yield of 59 FeCp 2 indicates that the 59 Fe atom reacts primarily at its point of genesis rather than after diffusion.
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