Ruthenium and Arsenic Electrode Potentials in Fused LiCl–KCl Eutectic | Zendy

T. Folkman | Zendy; James A. Plambeck | Zendy

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Ruthenium and Arsenic Electrode Potentials in Fused LiCl–KCl Eutectic

Author(s) -

T. Folkman,

James A. Plambeck

Publication year - 1972

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v72-615

Subject(s) - chemistry , standard electrode potential , eutectic system , electrode , ruthenium , electrode potential , inorganic chemistry , ionic bonding , platinum , molar ratio , analytical chemistry (journal) , electrochemistry , ion , organic chemistry , alloy , catalysis

Electrode potentials of the Ru(III)/Ru(0) and As(III)/As(0) systems were measured in dilute solutions of the ionic species in fused LiCl–KCl eutectic at 450 °C. Standard molar electrode potentials of these couples of −0.107 ± 0.007 V and −0.460 ± 0.017 V against a standard molar platinum electrode were calculated. The As(V)/As(III) potential was found to be beyond the potential range of the melt.

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