Oxidation of Hydrocarbons. III. Kinetics and Mechanism of the Oxidation of Arenes by Aqueous Sodium Dichromate | Zendy

Donald G. Lee | Zendy; Udo A. Spitzer | Zendy

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Oxidation of Hydrocarbons. III. Kinetics and Mechanism of the Oxidation of Arenes by Aqueous Sodium Dichromate

Author(s) -

Donald G. Lee,

Udo A. Spitzer

Publication year - 1971

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v71-461

Subject(s) - chemistry , aqueous solution , kinetics , inorganic chemistry , chromate conversion coating , sodium , oxidation process , chromic acid , ion , organic chemistry , chromium , chemical engineering , physics , quantum mechanics , engineering

The kinetics of the Oxidation of several sodium p-alkylbenzenesulfonates by aqueous dichromate have been studied under slightly acidic conditions (pH = 7.0 to 5.4). The results indicate that the only active oxidant under these conditions is the acid chromate ion, HCrO 4 − , and that the reaction probably involves a free radical process.

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