Absolute Rate Constants for Hydrocarbon Autoxidation. Part XX. Oxidation of Some Organic Sulfides | Zendy

J. A. Howard | Zendy; Stefan Korcek | Zendy

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Absolute Rate Constants for Hydrocarbon Autoxidation. Part XX. Oxidation of Some Organic Sulfides

Author(s) -

J. A. Howard,

Stefan Korcek

Publication year - 1971

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v71-356

Subject(s) - chemistry , autoxidation , radical , hydrocarbon , reaction rate constant , hydrogen atom abstraction , photochemistry , organic chemistry , kinetics , physics , quantum mechanics

Absolute rate constants for the liquid phase autoxidation of some organic sulfides at 30 °C have been measured. The reactivities of organic sulfides towards t-butylperoxy radicals are equal to or somewhat less than the reactivities of structurally analogous ethers. The α-alkylthiylalkylperoxy radicals appear to be about 3–5 times more reactive in hydrogen atom abstraction than the α-alkoxyalkylperoxy radicals.

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