z-logo
open-access-imgOpen Access
Aqueous Nonelectrolyte Solutions. Part VIII. Deuterium and Hydrogen Sulfides Solubilities in Deuterium Oxide and Water
Author(s) -
E. C. W. Clarke,
D. N. Glew
Publication year - 1971
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v71-116
Subject(s) - chemistry , solubility , deuterium , hydrogen sulfide , hydrogen , oxide , aqueous solution , inorganic chemistry , sulfide , heavy water , organic chemistry , sulfur , physics , quantum mechanics
A new apparatus is described in which the solubility of deuterium sulfide in deuterium oxide and of hydrogen sulfide in water have been determined with 0.1 % accuracy between 0 and 50 °C. Solubility equations are derived and the solubility standard thermodynamic function changes, together with their standard errors, are tabluated. Equal solubilities would occur at −1 °C. The solubility of hydrogen sulfide in water is greater than for deuterium sulfide in deuterium oxide, the solubility difference increases to a maximum at 40 °C and thence decreases at higher temperatures.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.
Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom