Open AccessAcid dependence and ion pairing in the anation reactions yielding iron(III) monosulfate
Author(s) -
F. L. Baker,
W. MacF. Smith
Publication year - 1970
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v70-522
Subject(s) - chemistry , reaction rate constant , kinetics , ion , inorganic chemistry , pairing , organic chemistry , physics , quantum mechanics , superconductivity
Stopped-flow studies of the kinetics of the a nation reaction yielding iron(III) monosulfate indicate a significant dependence of rate constant on acidity and also a dependence on iron concentrations. This is consistent with association constants for outer ion pair formation between the reactants which have about three times the Fuoss values.