Open AccessSome reactions of hydrazine with ruthenium compounds
Author(s) -
Frank Bottomley
Publication year - 1970
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v70-052
Subject(s) - ruthenium , chemistry , hydrazine (antidepressant) , inorganic chemistry , catalysis , organic chemistry , chromatography
Some reactions of hydrazine with pentachloroaquoruthenite(III) and ammine complexes of ruthenium(II) and ruthenium(III) have been investigated in acid, neutral, and alkaline solution. In neutral solution it has been shown that hydrazine monohydrochloride oxidized hexaammineruthenium(II) to hexaammineruthenium(III). In alkaline solution nitrogenpentaamrnineruthenium(II) was formed, and a mechanism for this reaction is postulated.
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