Molecular size distributions in multichain polymers: application of polymer theory to silicate melts
Author(s) -
C. R. Masson,
I. B. Smith,
S. G. Whiteway
Publication year - 1970
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v70-033
Subject(s) - silicate , polymer , chemistry , degree of polymerization , thermodynamics , polymerization , binary number , range (aeronautics) , silicate glass , distribution (mathematics) , degree (music) , statistical physics , mineralogy , materials science , physics , organic chemistry , mathematical analysis , arithmetic , mathematics , acoustics , composite material
Expressions developed previously by Flory and by the authors for molecular size distributions in branched polymers were used to derive theoretical curves of activity vs. composition in binary silicate melts. In contrast with curves based on the Flory distribution those derived from our result were in good agreement with experiment over the entire range of compositions up to the maximum degree of polymerization allowed by the theory. The comparison is illustrated for the systems PbO–SiO 2 and SnO–SiO 2 .
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