Open AccessFree radical halogenation of deuteriochloroform
Author(s) -
Dennis D. Tanner,
Melvyn W. Mosher,
Nigel J. Bunce
Publication year - 1969
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v69-782
Subject(s) - halogenation , chemistry , bromine , halide , hydrogen atom abstraction , halogen , abstraction , hydrogen halide , organic chemistry , photochemistry , hydrogen , computational chemistry , alkyl , philosophy , epistemology
The vapor phase chlorination and bromination of deuteriochloroform has been carried out in the presence of the corresponding hydrogen halide. The halogenations demonstrated the reversibility of the abstraction reaction by atomic bromine while the chlorination reactions failed to show any evidence for a reversible abstraction.
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