Abstraction of hydrogen from hydrogen sulfide by methyl radicals | Zendy

Peter Gray | Zendy; Alan A. Herod | Zendy; L. J. Leyshon | Zendy

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Abstraction of hydrogen from hydrogen sulfide by methyl radicals

Author(s) -

Peter Gray,

Alan A. Herod,

L. J. Leyshon

Publication year - 1969

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v69-106

Subject(s) - chemistry , radical , hydrogen atom abstraction , hydrogen sulfide , photochemistry , abstraction , hydrogen , methyl radical , reaction rate constant , radical substitution , radical disproportionation , medicinal chemistry , computational chemistry , organic chemistry , kinetics , catalysis , sulfur , disproportionation , philosophy , epistemology , physics , quantum mechanics

The methyl radical attack on H 2 S has been investigated briefly using azomethane as the radical source. The results indicate that the previous rate-constants for the abstraction reaction are too high and that CF 3 radicals may react with H 2 S faster than CH 3 radicals.

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