Electrical conductivities of quaternary ammonium salts in acetone.: Part I. Pressure and temperature effects | Zendy

William A. Adams | Zendy; Keith J. Laidler | Zendy

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Electrical conductivities of quaternary ammonium salts in acetone.: Part I. Pressure and temperature effects

Author(s) -

William A. Adams,

Keith J. Laidler

Publication year - 1968

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v68-328

Subject(s) - chemistry , tetramethylammonium , iodide , acetone , ammonium , inorganic chemistry , methyl iodide , dissociation (chemistry) , limiting , ammonium iodide , tetraethylammonium , atmospheric pressure , ion , analytical chemistry (journal) , organic chemistry , potassium , mechanical engineering , oceanography , geology , engineering

The equivalent conductivities of tetramethylammonium iodide, tetraethylammonium iodide, and tetra-n-propylammonium iodide in acetone solution were determined at concentrations from 1 to 10 × 10 −4 mole/liter and at temperatures of 25 to 55 °C and pressures from atmospheric to 1.1 kbar. The concentration dependence of the equivalent conductivities was analyzed by the Shedlovsky method. Limiting equivalent conductivities and ion-pair dissociation constants are tabulated.

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