H-atom scrambling and cis–trans isomerization of dideuteroethylene photosensitized by several organic compounds | Zendy

Shunichi Hirokami | Zendy; Shin Sato | Zendy

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H-atom scrambling and cis–trans isomerization of dideuteroethylene photosensitized by several organic compounds

Author(s) -

Shunichi Hirokami,

Shin Sato

Publication year - 1967

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v67-512

Subject(s) - chemistry , isomerization , mesitylene , benzene , photochemistry , fluorobenzene , toluene , excited state , atom (system on chip) , xylene , scrambling , computational chemistry , organic chemistry , atomic physics , linguistics , physics , philosophy , computer science , catalysis , embedded system

H-atom scrambling and cis–trans isomerization of dideuteroethylene have been observed with various photosensitizers: benzene, toluene, p-xylene, o-xylene, m-xylene, mesitylene, fluorobenzene, and benzotrifluoride. The pressure dependences are satisfactorily explained in terms of the two excited state mechanism previously proposed.Using Kassel's equation for the rate of unimolecular reactions, the energies of the triplet states of the sensitizers have been estimated. The values obtained coincide with the spectroscopic values.

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