Kinetic order with respect to solvent: Acid hydrolysis and preferential solvation of the Reineckate ion | Zendy

Cooper H. Langford | Zendy; John F. White | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Kinetic order with respect to solvent: Acid hydrolysis and preferential solvation of the Reineckate ion

Author(s) -

Cooper H. Langford,

John F. White

Publication year - 1967

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v67-494

Subject(s) - chemistry , solvation , solvation shell , solvolysis , solvent , inorganic chemistry , hydrolysis , ion , computational chemistry , organic chemistry

The nuclear magnetic resonance technique of preferential solvation analysis developed by Frankel, Stengle, and Langford is applied to determination of the composition of the solvation shell about trans-[Cr(NH 3 ) 2 (NCS) 4 ] − in acetone–water mixtures. The composition of the solvation shell is correlated with the rate of acid hydrolysis of the chromium complex. It emerges that the solvolysis reaction is second order with respect to the solvolytically reactive solvent, water. The mechanistic implications of the rate law are considered as is the significance of analysis of preferential solvation for the determination of kinetic order of solvolytic reactions.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research