Hydrogen abstraction by methyl radicals from benzene and the pressure dependence of the recombination of methyl radicals | Zendy

M. Krech | Zendy; S. J. W. Price | Zendy

Open Access

Hydrogen abstraction by methyl radicals from benzene and the pressure dependence of the recombination of methyl radicals

Author(s) -

M. Krech,

S. J. W. Price

Publication year - 1967

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v67-031

Subject(s) - chemistry , radical , benzene , hydrogen atom abstraction , methyl radical , extrapolation , hydrogen , photochemistry , medicinal chemistry , organic chemistry , mathematical analysis , mathematics

With dimethyl mercury and dimethyl cadmium as sources of methyl radicals, values of k 1 /k 2 1/2 for the reactions [Formula: see text] [Formula: see text]have been calculated from 471 to 527 °C over the pressure range 0.3 to 16.2 cm. Extrapolation to the effective infinite pressure region, where it is assumed that E 2 = 0, gives E 1 = 9.3 kcal mole −1 , log A 1 = 10.8 (cc mole −1 s −1 ).

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