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With dimethyl mercury and dimethyl cadmium as sources of methyl radicals, values of k 1 /k 2  1/2  for the reactions    [Formula: see text]    [Formula: see text]have been calculated from 471 to 527 °C over the pressure range 0.3 to 16.2 cm. Extrapolation to the effective infinite pressure region, where it is assumed that E 2  = 0, gives E 1  = 9.3 kcal mole −1 , log A 1  = 10.8 (cc mole −1  s −1 ).

Hydrogen abstraction by methyl radicals from benzene and the pressure dependence of the recombination of methyl radicals