PERMANGANATE–PERIODATE OXIDATION: PART VII. THE OXIDATION OF SOME ACYCLIC MONOTERPENES | Zendy

E. von Rudloff | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

PERMANGANATE–PERIODATE OXIDATION: PART VII. THE OXIDATION OF SOME ACYCLIC MONOTERPENES

Author(s) -

E. von Rudloff

Publication year - 1965

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v65-372

Subject(s) - chemistry , permanganate , periodate , geraniol , nerol , citronellol , organic chemistry , citronellal , autoxidation , reagent , potassium permanganate , aqueous solution , saponification , linalool , yield (engineering) , terpene , chromatography , catalysis , essential oil , materials science , metallurgy

The reaction of permanganate–periodate with 1-decene and 1-octadecene in aqueous suspension or media containing tert-butanol has been studied. C 10 -compounds are oxidized almost quantitatively with the aqueous reagent. Myrcene, cis-ocimene, citronellol, citronellal, citronellic acid, geraniol, nerol, linalool, and linalyl acetate are all oxidized in high yield to the predicted products. These can serve conveniently for chemical identification of the aliphatic terpenes when isolated from mixtures by gas–liquid chromatography. The reaction may also be useful in locating the 14 C-label in tracer studies.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research