THE NATURE OF ASSOCIATION BETWEEN MOLECULES OF N-METHYLPYRROLE | Zendy

Hugh J. Anderson | Zendy

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THE NATURE OF ASSOCIATION BETWEEN MOLECULES OF N-METHYLPYRROLE

Author(s) -

Hugh J. Anderson

Publication year - 1965

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v65-320

Subject(s) - chemistry , chemical shift , molecule , dilution , dipole , cyclohexane , hydrogen bond , equilibrium constant , dimer , computational chemistry , thermodynamics , organic chemistry , physics

The dilution of N-methylpyrrole by an inert solvent causes a change in the values of the proton chemical shifts which has been interpreted to support a "closed cyclic dimer" type of association between molecules. Equilibrium constants have been computed for the monomer–dimer system at two temperatures. The proton chemical shifts have been determined for the pure liquid at a series of temperatures covering a wide range. The effects of dilution in several different solvents have also been investigated.

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