FLUORIDE COMPLEXES OF GERMANIUM (IV) IN AQUEOUS SOLUTION | Zendy

R. L. Benoit | Zendy; J. Place | Zendy

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FLUORIDE COMPLEXES OF GERMANIUM (IV) IN AQUEOUS SOLUTION

Author(s) -

R. L. Benoit,

J. Place

Publication year - 1963

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v63-165

Subject(s) - chemistry , germanium , perchloric acid , aqueous solution , fluoride , solubility , inorganic chemistry , potentiometric titration , solvent , extraction (chemistry) , solvent extraction , analytical chemistry (journal) , organic chemistry , ion , silicon

The germanium (IV) – fluoride species in various acid media have been investigated by solvent extraction, solubility, and potentiometric methods. The results are interpreted in terms of a series of mononuclear fluorohydroxygermanium (IV) species in which the number of fluorides bound per germanium tends to a maximum value of 5. The formation curve in 0.50 M perchloric acid is explained in terms of stability constants of species [Formula: see text] and [Formula: see text]

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