SODIUM CHELATES OF ETHYLENEDIAMINETETRAACETIC ACID
Author(s) -
Vladimír Palatý
Publication year - 1963
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v63-004
Subject(s) - chemistry , ethylenediaminetetraacetic acid , chelation , sodium , inorganic chemistry , stability constants of complexes , glass electrode , electrode , electrochemistry , organic chemistry , ion , reference electrode
The stability constant of the sodium chelate of EDTA was determined by means of a sodium-sensitive glass electrode. It appears that a hydrogen chelate of the formula NaHY 2− is formed in the neutral solution of EDTA, but is very unstable. The stability constants, pK NaY = −2.61 and pK NaHY = 0.03, are comparable to the value obtained by Schwarzenbach and Ackermann under different experimental conditions by a less sensitive method.
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