Open AccessTHE THERMAL DECOMPOSITION OF HEXAFLUOROAZOMETHANE
Author(s) -
Elizabeth Leventhal,
Charles R. Simonds,
Colin Steel
Publication year - 1962
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v62-139
Subject(s) - chemistry , thermal decomposition , pyrolysis , reaction rate constant , homogeneous , decomposition , nitrogen , analytical chemistry (journal) , thermodynamics , kinetics , organic chemistry , physics , quantum mechanics
The pyrolysis of hexafluoroazomethane has been studied in a static system between 0.3 mm and 73 mm and 572 °K and 634 °K by measuring the rate of nitrogen formation. The rate constant of the high-pressure homogeneous reaction is given by k = 10 16.17±0.15 exp (−55,200 ± 400/RT) sec −1
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