METAL OXIDE ALKOXIDE POLYMERS: PART IV. THE HYDROLYSIS OF SOME TANTALUM ALKOXIDES | Zendy

D. C. Bradley | Zendy; H. Holloway | Zendy

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METAL OXIDE ALKOXIDE POLYMERS: PART IV. THE HYDROLYSIS OF SOME TANTALUM ALKOXIDES

Author(s) -

D. C. Bradley,

H. Holloway

Publication year - 1962

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v62-011

Subject(s) - tantalum , chemistry , hydrolysis , alkoxide , polymer , oxide , metal , polymerization , inorganic chemistry , polymer chemistry , organic chemistry , catalysis

Ebulliometric studies on the hydrolysis of tantalum pentaalkoxides Ta(OR) 5 , where R = Me, Pr n , Bu n , and Bu s , have furnished important data on the polymeric nature of tantalum oxide alkoxides. It is shown from the variation of number-average degrees of polymerization as a function of degree of hydrolysis that the polymers conform to certain structural models. The structural models involve 6-co-ordinated tantalum.

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