PROTON MAGNETIC RESONANCE SHIFTS FOR THE H2O–SO3 SYSTEM AND SOME ELECTROLYTE SOLUTIONS IN SULPHURIC ACID | Zendy

R. J. Gillespie | Zendy; R. F. White | Zendy

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PROTON MAGNETIC RESONANCE SHIFTS FOR THE H₂O–SO₃ SYSTEM AND SOME ELECTROLYTE SOLUTIONS IN SULPHURIC ACID

Author(s) -

R. J. Gillespie,

R. F. White

Publication year - 1960

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v60-191

Subject(s) - chemistry , electrolyte , proton magnetic resonance , aqueous solution , proton , solvent , polarization (electrochemistry) , ionization , inorganic chemistry , chemical shift , analytical chemistry (journal) , nuclear magnetic resonance , ion , organic chemistry , nuclear physics , physics , electrode

Proton magnetic resonance shifts have been measured for the H 2 O–SO 3 system. The results have been used to calculate the degree of ionization of water in solutions containing excess sulphuric acid. The shifts produced by a number of electrolytes in sulphuric acid have also been measured. The results are interpreted in terms of solute–solvent interactions, particularly polarization and hydrogen bonding, and are compared with the results of similar previous measurements on aqueous solutions.

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