GRISEOVIRIDIN: THE C6 FRAGMENT | Zendy

P. de Mayo | Zendy; A. Jon Stoessl | Zendy

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GRISEOVIRIDIN: THE C₆ FRAGMENT

Author(s) -

P. de Mayo,

A. Jon Stoessl

Publication year - 1960

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v60-133

Subject(s) - chemistry , fragment (logic) , sulfur , product (mathematics) , hydrolysis , degradation (telecommunications) , atom (system on chip) , stereochemistry , hydrolytic degradation , organic chemistry , algorithm , embedded system , telecommunications , geometry , mathematics , computer science

The structure of a hydrolytic degradation product from griseoviridin, isolated as the 2,4-dinitrophenylhydrazone, has been shown, by synthesis, to be IV. A by-product of the synthesis was the stereoisomeric 2,4-dinitrophenylhydrazone. This establishes IX as a part structure of griseoviridin. Evidence is provided that the previously proposed structural environment of the sulphur atom is incorrect, and that the sulphur may, in fact, be attached to the C 6 fragment.

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