Open AccessTHE SYNTHESIS OF CRYPTOPLEURINE AND RELATED PHENANTHROQUINOLIZIDINES
Author(s) -
Paolo Marchini,
B. Belleau
Publication year - 1958
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v58-081
Subject(s) - chemistry , biogenesis , alkaloid , sequence (biology) , stereochemistry , total synthesis , combinatorial chemistry , biochemistry , gene
The synthesis of the alkaloid cryptopleurine has been accomplished by a sequence involving as the key step the cyclization of amino acid XII. It was established that the approach is applicable to the synthesis of simpler phenanthroquinolizidines such as IV. The biogenesis of the alkaloid is briefly discussed.
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