THE GAS PHASE REACTION OF METHYL RADICALS WITH HEXAFLUOROACETONE | Zendy

G. O. Pritchard | Zendy; E. W. R. Steacie | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

THE GAS PHASE REACTION OF METHYL RADICALS WITH HEXAFLUOROACETONE

Author(s) -

G. O. Pritchard,

E. W. R. Steacie

Publication year - 1957

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v57-162

Subject(s) - hexafluoroacetone , chemistry , radical , steric effects , gas phase , decomposition , photochemistry , activation energy , thermal decomposition , steric factor , reaction mechanism , phase (matter) , organic chemistry , computational chemistry , catalysis

The photolytic and thermal decomposition of azomethane in the presence of hexafluoroacetone produces small amounts of fluorinated products, mainly fluoroform. The mechanism of this and related reactions is discussed. It is concluded that the proposed reaction.[Formula: see text]has an activation energy of about 6 kcal./mole, with a steric factor of about 10 −5 .

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research