THEORY OF THE TRANSIENT PHASE IN KINETICS, WITH SPECIAL REFERENCE TO ENZYME SYSTEMS | Zendy

Keith J. Laidler | Zendy

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THEORY OF THE TRANSIENT PHASE IN KINETICS, WITH SPECIAL REFERENCE TO ENZYME SYSTEMS

Author(s) -

Keith J. Laidler

Publication year - 1955

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v55-195

Subject(s) - chemistry , transient (computer programming) , steady state (chemistry) , kinetics , substrate (aquarium) , thermodynamics , kinetic energy , phase (matter) , transient state , classical mechanics , organic chemistry , physics , oceanography , engineering , computer science , electrical engineering , geology , operating system

The steady-state hypothesis is discussed for enzyme systems, and the conditions under which the steady-state equations will be valid over the main course of the reaction are obtained. It is shown that this is so if the substrate is in great excess, and also under several other circumstances. Equations are derived for the kinetic behavior during the transient phase of the reaction. Two-substrate systems, and the special case of catalase, are considered.

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