Adsorption of a jet fuel on a model organic–clay soil: Application of small angle neutron scatteringA paper submitted to the Journal of Environmental Engineering and Science.
Author(s) -
H. J. M. Hanley,
Timothy E. Payne
Publication year - 2009
Publication title -
canadian journal of civil engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 62
eISSN - 1208-6029
pISSN - 0315-1468
DOI - 10.1139/l09-007
Subject(s) - adsorption , environmental remediation , clay minerals , dispersion (optics) , chemical engineering , bromide , organic matter , environmental chemistry , chemistry , environmental science , materials science , contamination , mineralogy , organic chemistry , physics , engineering , ecology , optics , biology
Small angle neutron scattering (SANS) data are reported from a system that models the contamination of a clay/organic matter soil from a fuel spillage. The soil was represented as an aqueous dispersion of the synthetic clay mineral Laponite coated with lysine, and the contaminant was a representative jet fuel, quadricyclane, mixed with the detergent cetyltrimethylammonium bromide (CTAB). The adsorbed surface coverage on the clay was estimated. It is shown that the presence of adsorbed lysine considerably enhances the subsequent adsorption of both CTAB and quadricyclane. It is demonstrated that the SANS technique can contribute to the general problem of environmental remediation and retention by probing the interactions of pollutants and clay surfaces. © 2008, National Research Council Canad
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