Water transfer to the deep mantle through hydrous, Al-rich silicates in subduction zones

Constraining deep-water recycling along subduction zones is a first-order problem to understand how Earth has maintained a hydrosphere over billions of years that created conditions for a habitable planet. The pressure-temperature stability of hydrous phases in conjunction with slab geotherms determines how much H2O leaves the slab or is transported to the deep mantle. Chlorite-rich, metasomatic rocks that form at the slab-mantle interface at 50–100 km depth represent an unaccounted, H2O-rich reservoir in subduction processes. Through a series of high-pressure experiments, we investigated the fate of such chlorite-rich rocks at the most critical conditions for subduction water recycling (5–6.2 GPa, 620–800 °C) using two different natural ultramafic compositions. Up to 5.7 GPa, 740 °C, chlorite breaks down to an anhydrous peridotite assemblage, and H2O is released. However, at higher pressures and lower temperatures, a hydrous Al-rich silicate (11.5 Å phase) is an important carrier to enable water transfer to the deep mantle for cold subduction zones. Based on the new phase diagrams, it is suggested that the deep-water cycle might not be in secular equilibrium.