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The catabolism of phosphonic acids occurs inEscherichia coli by the carbon-phosphorus lyase pathway, which is governed by the 14-cistronphn operon. Here, several compounds are shown to accumulate in strains ofE. coli with genetic blocks in variousphn cistrons when the strains are fed with phosphonate.

Accumulation of Intermediates of the Carbon-Phosphorus Lyase Pathway for Phosphonate Degradation in phn Mutants of Escherichia coli