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Effect of Octamethylcyclotetrasiloxane on Methylation of Bismuth by Methanosarcina barkeri
Author(s) -
Klaus Michalke,
Jörg Meyer,
Reinhard Hensel
Publication year - 2006
Publication title -
applied and environmental microbiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.552
H-Index - 324
eISSN - 1070-6291
pISSN - 0099-2240
DOI - 10.1128/aem.00694-06
Subject(s) - methanosarcina barkeri , octamethylcyclotetrasiloxane , lasalocid , monensin , bismuth , chemistry , methylation , environmental chemistry , membrane , methanogenesis , biochemistry , methane , organic chemistry , ionophore , polymer chemistry , gene
Octamethylcyclotetrasiloxane (OMCTS), a common constituent of household products, triggers the transformation of bismuth to the volatile toxic derivative trimethylbismuth by Methanosarcina barkeri, which is a representative member of the sewage sludge microflora. Comparative studies with the ionophores monensin and lasalocid, which induce effects similar to those observed for OMCTS, indicated that the stimulation of bismuth methylation is not specific for the siloxane and suggested that the stimulation observed is mainly due to facilitated membrane permeation of the metal ion.

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