Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses
Author(s) -
Jingwei Hou,
Peng Chen,
Atul Shukla,
Andraž Krajnc,
Tiesheng Wang,
Xuemei Li,
Rana Doasa,
Luiz H. G. Tizei,
Bun Chan,
Duncan N. Johnstone,
Rijia Lin,
Tobias U. Schülli,
Isaac Martens,
Dominique Appadoo,
Mark S’ Ari,
Zhiliang Wang,
Tong Wei,
ShihChun Lo,
Mingyuan Lu,
Shichun Li,
Ebinazar B. Namdas,
Gregor Mali,
Anthony K. Cheetham,
Sean M. Collins,
Vicki Chen,
Lianzhou Wang,
Thomas D. Bennett
Publication year - 2021
Publication title -
science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 12.556
H-Index - 1186
eISSN - 1095-9203
pISSN - 0036-8075
DOI - 10.1126/science.abf4460
Subject(s) - materials science , halide , perovskite (structure) , sintering , passivation , photoluminescence , light emitting diode , chemical engineering , composite material , optoelectronics , inorganic chemistry , chemistry , layer (electronics) , engineering
Stable emission in glass Lead halide perovskites can exhibit bright, narrow band photoluminescence but have stability issues related to formation of inactive phases and the loss of lead ions. Houet al . show that the black, photoactive phase of cesium lead iodide can be stabilized by forming a composite with a glassy phase of a metal-organic framework through liquid-phase sintering. The photoluminescence is at least two orders of magnitude greater than that of the pure perovskite. The glass stabilizes the perovskite under high laser excitation, and about 80% of the photoluminescence was maintained after 10,000 hours of water immersion. —PDS
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