Accelerating water dissociation in bipolar membranes and for electrocatalysis
Author(s) -
Sebastian Z. Oener,
M. J. Foster,
Shan W. Boettcher
Publication year - 2020
Publication title -
science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 12.556
H-Index - 1186
eISSN - 1095-9203
pISSN - 0036-8075
DOI - 10.1126/science.aaz1487
Subject(s) - overpotential , dissociation (chemistry) , electrocatalyst , electrolysis of water , catalysis , hydrogen , chemistry , self ionization of water , hydroxide , membrane , inorganic chemistry , oxygen , electrolysis , water splitting , ion , chemical engineering , electrolyte , electrochemistry , electrode , organic chemistry , engineering , biochemistry , photocatalysis
Easing water apart Traditional setups for splitting water into hydrogen and oxygen operate either in acid or in base. A bipolar membrane can potentially enhance efficiency by bridging acidic hydrogen evolution to basic oxygen evolution. Oeneret al. undertook a systematic study of how catalysts paired with such a membrane might accelerate the preliminary step of water dissociation into protons and hydroxide ions. Using insights from this study for optimal catalyst integration, they were able to substantially lower the overpotential of a bipolar membrane electrolyzer.Science , this issue p.1099
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