Large negative thermo-optic coefficients of a lead halide perovskite

Lead halide perovskites are promising semiconductors for high-performance photonic devices. Because the refractive index determines the optimal design and performance limit of the semiconductor devices, the refractive index and its change upon external modulations are the most critical properties for advanced photonic applications. Here, we report that the refractive index of halide perovskite CHNHPbCl shows a distinct decrease with increasing temperature, i.e., a large negative thermo-optic coefficient, which is opposite to those of conventional inorganic semiconductors. By using this negative coefficient, we demonstrate the compensation of thermally induced optical phase shifts occurring in conventional semiconductors. Furthermore, we observe a large and slow refractive index change in CHNHPbCl during photoirradiation and clarify its origin to be a very low thermal conductivity supported by theoretical analysis. The giant thermo-optic response of CHNHPbCl facilitates efficient phase modulation of visible light.