Rapid isotopic exchange in nanoparticles | Zendy

Papri Chakraborty | Zendy; Abhijit Nag | Zendy; Ganapati Natarajan | Zendy; Nayanika Bandyopadhyay | Zendy; Ganesan Paramasivam | Zendy; Manoj Kumar Panwar | Zendy; J. Chakrabarti | Zendy; Thalappil Pradeep | Zendy

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Rapid isotopic exchange in nanoparticles

Author(s) -

Papri Chakraborty,

Abhijit Nag,

Ganapati Natarajan,

Nayanika Bandyopadhyay,

Ganesan Paramasivam,

Manoj Kumar Panwar,

J. Chakrabarti,

Thalappil Pradeep

Publication year - 2019

Publication title -

science advances

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.928

H-Index - 146

ISSN - 2375-2548

DOI - 10.1126/sciadv.aau7555

Subject(s) - nanoparticle , nanotechnology , chemistry , computer science , materials science

Rapid solution-state exchange dynamics in nanoscale pieces of matter is revealed, taking isotopically pure atomically precise clusters as examples. As two isotopically pure silver clusters made of Ag and Ag are mixed, an isotopically mixed cluster of the same entity results, similar to the formation of HDO, from HO and DO. This spontaneous process is driven by the entropy of mixing and involves events at multiple time scales.

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