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Harmonic? Anharmonic? Inharmonic?
Author(s) -
Neville H. Fletcher
Publication year - 2002
Publication title -
american journal of physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.541
H-Index - 99
eISSN - 1943-2909
pISSN - 0002-9505
DOI - 10.1119/1.1509419
Subject(s) - anharmonicity , physics , harmonic oscillator , harmonic , atomic physics , spectrum (functional analysis) , limit (mathematics) , spectral line , vibration , spectroscopy , nonlinear system , confusion , quantum mechanics , quantum electrodynamics , mathematical analysis , psychology , mathematics , psychoanalysis
In molecular spectroscopy, an anharmonic oscillator has a nonparabolic potential which results in a nonharmonic absorption spectrum, but the same oscillator treated classically has a precisely harmonic vibrational spectrum. To avoid confusion, it is suggested that such an oscillator should simply be called nonlinear. The term “inharmonic” is suggested as an appropriate descriptor for classical oscillators, such as metal bars, that have nonharmonic vibrational spectra even in the linear limit of small vibrations.

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