Open AccessRadiolysis of frozen methanol by heavy cosmic ray and energetic solar particle analogues
Author(s) -
de Barros A. L. F.,
Domaracka A.,
Andrade D. P. P.,
Boduch P.,
Rothard H.,
da Silveira E. F.
Publication year - 2011
Publication title -
monthly notices of the royal astronomical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.058
H-Index - 383
eISSN - 1365-2966
pISSN - 0035-8711
DOI - 10.1111/j.1365-2966.2011.19587.x
Subject(s) - physics , dissociation (chemistry) , cosmic ray , irradiation , ion , atomic physics , radiolysis , astrochemistry , helium , hydrogen , methanol , interstellar medium , astrophysics , nuclear physics , chemistry , quantum mechanics , galaxy , organic chemistry
ABSTRACT The chemical and physical effects induced by fast heavy ion irradiation on frozen pure methanol (CH 3 OH) at 15 K were studied. These energetic ions can simulate the energy transfer processes that occur by cosmic ray irradiation of interstellar ices, comets and icy Solar system bodies. The analysis was made by infrared spectroscopy (Fourier transform infrared) before and after irradiation, with 16‐MeV 16 O 5+ , 220‐MeV 16 O 7+ , 606‐MeV 65 Zn 20+ and 774‐MeV 86 Kr 31+ ion beams. Integrated values of the absorbance of the main methanol bands were determined. The induced CH 3 OH dissociation gives rise to the formation of molecular species, particularly H 2 CO, CH 2 OH, CH 4 , CO, CO 2 , HCO and HCOOCH 3 . Their formation and dissociation cross‐sections were determined. H 2 CO and CH 4 molecules are in general the most abundant new products of the four beams analysed. Except for the HCO and CH 2 OH species, cross‐sections increased with the electronic stopping power, roughly as σ∼ S 3/2 e . The G values for CH 3 OH destruction by fast heavy ion irradiation with Zn and Kr beams were found to be considerably larger than those for oxygen, helium or hydrogen. As an astrophysical implication, the S 3/2 e power law should be very helpful for predicting the CH 3 OH formation and dissociation cross‐sections for other ion beam projectiles and energies. As astrophysical point of view, the analysis of the predictions reveals the unexpected importance of iron and some other heavy ion constituents of cosmic rays in astrochemistry.