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The Ag I  atom in the polycationic salt, {[Ag(C 11 H 11 N 3 O)]NO 3 }  n  , shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO 3   −  counter-ions surround the polymeric chain and inter­act only weakly with it [Ag⋯O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O—H⋯O and N—H⋯O hydrogen bonds.

catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ2N1:N4)aminomethyl]phenol] nitrate]

catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ²N¹:N⁴)aminomethyl]phenol] nitrate]