2‐[( Z )‐(2,5‐Dichlorophenyl)iminomethyl]‐5‐(diethylamino)phenol | Zendy

Jasinski Jerry P. | Zendy; Butcher Ray J. | Zendy; Narayana B. | Zendy; Swamy M. T. | Zendy; Yathirajan H. S. | Zendy

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2‐[( Z )‐(2,5‐Dichlorophenyl)iminomethyl]‐5‐(diethylamino)phenol

Author(s) -

Jasinski Jerry P.,

Butcher Ray J.,

Narayana B.,

Swamy M. T.,

Yathirajan H. S.

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536807055791

Subject(s) - stacking , phenol , hydrogen bond , chemistry , crystallography , aromaticity , crystal (programming language) , crystal structure , atom (system on chip) , bioinformatics , stereochemistry , medicinal chemistry , molecule , organic chemistry , computer science , embedded system , biology , programming language

In the title molecule, C 17 H 18 Cl 2 N 2 O, the angle between the mean planes of the 2,5‐dichlorophenylimino and phenol groups is 19.5 (5)°. The two ethyl groups adopt a synclinal conformation. The crystal structure is stabilized by intermolecular π–π stacking interactions between adjacent 2,5‐dichlorophenyl rings, the distance between the centroids of interacting rings being 3.860 (8) Å. The molecules are stacked parallel to the a axis. In addition, an O—H...N intramolecular hydrogen‐bonding interaction between the phenol H atom and imino N atom is observed.

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