1‐(1,5‐Dimethylhexyl)‐3a,5b,12a,14a‐tetramethyl‐2,3,3a,4,5,5a,5b,11,12,13,14,14a‐dodecahydro‐1 H ,12a H ‐cyclopenta[1,2]phenanthro[7,8‐ b ]indole | Zendy

LópezRodríguez Matías | Zendy; Mazoir Noureddine | Zendy; Daoubi Mourad | Zendy; Reina Matías | Zendy; Benharref Ahmed | Zendy

Open Access

1‐(1,5‐Dimethylhexyl)‐3a,5b,12a,14a‐tetramethyl‐2,3,3a,4,5,5a,5b,11,12,13,14,14a‐dodecahydro‐1 H ,12a H ‐cyclopenta[1,2]phenanthro[7,8‐ b ]indole

Author(s) -

LópezRodríguez Matías,

Mazoir Noureddine,

Daoubi Mourad,

Reina Matías,

Benharref Ahmed

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536807053913

Subject(s) - triterpene , stereocenter , indole test , chemistry , ring (chemistry) , stereochemistry , derivative (finance) , crystallography , organic chemistry , enantioselective synthesis , medicine , alternative medicine , pathology , financial economics , economics , catalysis

The title compound, C 35 H 51 N, is a semi‐synthesized derivative obtained from 4α,14α‐dimethyl‐5α‐cholest‐8‐en‐3β‐ol, a major triterpene isolated from Euphorbia officinarum latex. The molecular structure was established by 1 H and 13 C NMR spectroscopy and confirmed as having the β stereochemistry at the new C11b stereocenter by single‐crystal X‐ray diffraction. The planar indole group is folded over the extended tetracyclic perhydrocyclopentanephenanthrene triterpene skeleton. There are no π–π interactions between the indole ring systems.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research