Open Access(6‐Acetoxy‐2‐acetylphenyl‐κ 2 C 1 , O 1 )tetracarbonylmanganese(I)
Author(s) -
Fester Victor D.,
Main Lyndsay,
Nicholson Brian K.
Publication year - 2007
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536807047605
Subject(s) - steric effects , intramolecular force , chemistry , benzene , crystallography , stereochemistry , medicinal chemistry , organic chemistry
The title compound, [Mn(C 10 H 9 O 3 )(CO) 4 ], is formed by orthomanganation of 3′‐acetoxyacetophenone at the sterically crowded ortho site. The atoms of the benzene and the cyclometallated rings are coplanar to within <0.018 Å, and there are no significant intramolecular interactions between the Mn(CO) 4 group and the adjacent acetoxy group.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom