Open AccessPoly[μ 2 ‐ l ‐alanine‐μ 3 ‐nitrato‐sodium(I)]
Author(s) -
Van Hecke Kristof,
Cartuyvels Els,
ParacVogt Tatja.,
GörllerWalrand Christiane,
Van Meervelt Luc
Publication year - 2007
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536807039438
Subject(s) - molybdate , chemistry , sodium molybdate , alanine , carboxylate , denticity , aqueous solution , sodium , trigonal bipyramidal molecular geometry , medicinal chemistry , sodium nitrate , atom (system on chip) , stereochemistry , inorganic chemistry , sodium salt , crystallography , amino acid , crystal structure , organic chemistry , biochemistry , computer science , embedded system
The title compound, [Na(NO 3 )(C 3 H 7 NO 2 )] n , was obtained unintentionally as the product of an attempted reaction of sodium molybdate in aqueous solution and the amino acid l ‐alanine (ala), in order to obtain a γ‐type octamolybdate, Na 4 [Mo 8 O 26 (ala) 2 ].18H 2 O, coordinated by l ‐alanine. The coordination geometry around the Na atom can be considered as trigonal–bipyramidal, with three bidentate nitrate anions coordinating through their O atoms and two l ‐alanine molecules each coordinating through one carboxylate O atom.
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