Bis{2‐[(dimethylamino‐κ N )methyl]benzenethiolato‐κ S }zinc(II) | Zendy

Chrzanowski Lars S. von | Zendy; Lutz Martin | Zendy; Spek Anthony L. | Zendy; Kleijn Henk | Zendy; Koten Gerard van | Zendy

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Bis{2‐[(dimethylamino‐κ N )methyl]benzenethiolato‐κ S }zinc(II)

Author(s) -

Chrzanowski Lars S. von,

Lutz Martin,

Spek Anthony L.,

Kleijn Henk,

Koten Gerard van

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536807027183

Subject(s) - denticity , thiol , benzene , chemistry , zinc , tetra , stereochemistry , medicinal chemistry , center (category theory) , crystal (programming language) , crystal structure , bioinformatics , crystallography , organic chemistry , computer science , biology , programming language

In the title compound, [Zn(C 9 H 12 NS) 2 ], the Zn II center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2‐[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the Δ form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C—H...π contacts connect the molecules into a two‐dimensional network.

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