fac , cis ‐Bromidotricarbonylbis(tribenzylphosphine)rhenium(I) | Zendy

Beckett Michael A. | Zendy; Light Mark E. | Zendy; Brassington David S. | Zendy; ThorntonPett Mark | Zendy

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fac , cis ‐Bromidotricarbonylbis(tribenzylphosphine)rhenium(I)

Author(s) -

Beckett Michael A.,

Light Mark E.,

Brassington David S.,

ThorntonPett Mark

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s160053680700726x

Subject(s) - rhenium , recrystallization (geology) , chemistry , octahedron , hexane , cis–trans isomerism , trans effect , octahedral molecular geometry , stereochemistry , medicinal chemistry , crystallography , crystal structure , inorganic chemistry , organic chemistry , geology , paleontology

Crystals of the title compound, fac , cis ‐[ReBr(C 21 H 21 P) 2 (CO) 3 ], were obtained by recrystallization of a sample from CHCl 3 layered with hexane. The geometry about the d 6 Re I centre is (distorted) octahedral with the three CO ligands fac and the two tribenzylphosphine ligands cis . In accordance with the trans influence, the Re—C bond trans to Br is significantly shorter than those trans to the organophosphine ligands.

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