Di‐μ‐chloro‐bis({2‐[(2‐hydroxyethyl)iminomethyl]phenolato‐κ 3  N , O , O ′}nickel(II)) methanol solvate | Zendy

Van Hecke Kristof | Zendy; Nockemann Peter | Zendy; Binnemans Koen | Zendy; Van Meervelt Luc | Zendy

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Di‐μ‐chloro‐bis({2‐[(2‐hydroxyethyl)iminomethyl]phenolato‐κ 3 N , O , O ′}nickel(II)) methanol solvate

Author(s) -

Van Hecke Kristof,

Nockemann Peter,

Binnemans Koen,

Van Meervelt Luc

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536807002292

Subject(s) - nickel , chemistry , schiff base , imine , methanol , atom (system on chip) , chelation , medicinal chemistry , crystallography , coordination geometry , square pyramidal molecular geometry , stereochemistry , crystal structure , polymer chemistry , molecule , inorganic chemistry , catalysis , hydrogen bond , organic chemistry , computer science , embedded system

The title compound, [Ni 2 Cl 2 (C 9 H 10 NO 2 ) 2 ]·CH 3 OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni II atom can be considered as distorted square‐pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

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