Tricarbonyl[tris(pyrazol‐1‐yl)methanesulfonato‐κ 3  N , N ′, N ′′]rhenium(I) acetone solvate | Zendy

Kurz Philipp | Zendy; Spingler Bernhard | Zendy; Kunz Peter | Zendy; Alberto Roger | Zendy

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Tricarbonyl[tris(pyrazol‐1‐yl)methanesulfonato‐κ 3 N , N ′, N ′′]rhenium(I) acetone solvate

Author(s) -

Kurz Philipp,

Spingler Bernhard,

Kunz Peter,

Alberto Roger

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806055942

Subject(s) - tris , chemistry , ligand (biochemistry) , rhenium , acetone , medicinal chemistry , solvent , yield (engineering) , methane sulfonate , chelation , thallium , crystal structure , inorganic chemistry , crystallography , organic chemistry , materials science , receptor , biochemistry , mutant , metallurgy , gene

The title compound, [Re(C 10 H 9 N 6 O 3 S)(CO) 3 ]·C 3 H 6 O, was prepared in almost quantitative yield by reaction of Re(CO) 5 Br with the thallium salt of the tris(pyrazolyl)methanesulfonate (tpms) ligand. It shows a slightly distorted octahedral geometry for the fac ‐Re(CO) 3 N 3 unit, with the ligand forming three six‐membered N‐bonded chelate rings. A C—H⋯O interaction between the main molecule and the solvent molecule helps to establish the crystal packing.

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