Open Accesstrans ‐Bromohydridobis(triphenylphosphine)platinum(II)
Author(s) -
Sivaramakrishna Akella,
Su Hong,
Moss John R.
Publication year - 2007
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s160053680605358x
Subject(s) - phosphine , triphenylphosphine , hydride , crystallography , bromide , platinum , chemistry , bent molecular geometry , neutron diffraction , bond length , atom (system on chip) , stereochemistry , crystal structure , inorganic chemistry , metal , organic chemistry , catalysis , computer science , embedded system
The title compound, [PtBrH(C 18 H 15 P) 2 ], has a square‐planar environment around the Pt atom, with the hydride and bromide ligands being exactly collinear with Pt since they all lie on a crystallographic twofold rotation axis, and with mutually trans triphenylphosphine ligands with a P—Pt—P bond angle that is slightly bent towards the hydride [P—Pt—P = 170.81 (5)°]. The Pt—H distance (1.610 Å) is in good agreement with those found in structures determined by neutron diffraction.
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