(2 E )‐1‐(2,4‐Dichlorophenyl)‐3‐[4‐(methylsulfanyl)phenyl]prop‐2‐en‐1‐one | Zendy

Butcher Ray J. | Zendy; Yathirajan H. S. | Zendy; Narayana B. | Zendy; Mithun A. | Zendy; Sarojini B. K. | Zendy

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(2 E )‐1‐(2,4‐Dichlorophenyl)‐3‐[4‐(methylsulfanyl)phenyl]prop‐2‐en‐1‐one

Author(s) -

Butcher Ray J.,

Yathirajan H. S.,

Narayana B.,

Mithun A.,

Sarojini B. K.

Publication year - 2007

Publication title -

acta crystallographica section e

Language(s) - English

Resource type - Journals

ISSN - 1600-5368

DOI - 10.1107/s1600536806050069

Subject(s) - dihedral angle , hydrogen bond , benzene , nonlinear optical , chemistry , crystallography , chalcone , crystal structure , crystal (programming language) , stereochemistry , molecule , nonlinear system , physics , organic chemistry , computer science , quantum mechanics , programming language

The title compound, C 16 H 12 Cl 2 OS, crystallizes in a non‐centrosymmetric space group and shows a significant nonlinear optical activity. The source of the optical activity lies in the twist of the chalcone backbone, as exemplified by the dihedral angle of 42.45 (6)° between the two benzene rings. Weak intermolecular C—H⋯O hydrogen bonds may contribute to the stabilization of the crystal structure.

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