Open Accessμ 3 ‐Oxo‐hexa‐μ 2 ‐pivalato‐(pivalic acid‐κ O )bis(pyridine‐κ N )trimanganese(III,III,II)
Author(s) -
Sarı Musa,
Poyraz Mehmet,
Büyükgüngör Orhan,
Can Roderick D.
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806048343
Subject(s) - pivalic acid , hexa , pyridine , chemistry , crystallography , atom (system on chip) , stereochemistry , medicinal chemistry , catalysis , organic chemistry , computer science , embedded system
The asymmetric unit of the title compound, [Mn 3 (C 5 H 9 O 2 ) 6 O(C 5 H 5 N) 2 (C 5 H 10 O 2 )], comprises two independent and similar [Mn III 2 Mn II O{(CH 3 ) 3 CCO 2 } 6 (py) 2 (CH 3 ) 3 CCOOH] (py = pyridine) molecules each with an Mn 3 (μ 3 ‐O) core. In each molecule, the Mn atoms have octahedral geometry with two coordinated pyridines bonded to two Mn III and a terminal pivalic acid coordinated to the Mn II atom.