Open Accesscatena ‐Poly[[[diaquacadmium(II)]‐μ‐2,2′‐bipyridine‐6,6′‐dicarboxylato] dihydrate]
Author(s) -
Knight James C.,
Amoroso Angelo J.,
Edwards Peter G.,
Ooi LiLing
Publication year - 2006
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536806046423
Subject(s) - pentagonal bipyramidal molecular geometry , chemistry , cadmium , crystallography , monomer , polyhedron , bipyramid , divalent , bipyridine , stereochemistry , crystal structure , polymer , combinatorics , mathematics , organic chemistry
The title hydrated 2,2′‐bipyridine‐6,6′‐dicarboxylate–cadmium(II) complex, {[Cd(C 12 H 2 N 2 O 4 )(H 2 O) 2 ]·2H 2 O} n , crystallizes with eight oxygen‐bridged monomer units in the unit cell. The divalent cadmium ion is seven‐coordinate, and the coordination polyhedron can best be described as slightly distorted pentagonal–bipyramidal.